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Threefold coordinated germanium in a GeO2 melt - Nature Communications

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Threefold coordinated germanium in a GeO2 melt - Nature Communications

The local structure around germanium is a fundamental issue in material science and geochemistry. In the prevailing viewpoint, germanium in GeO2 melt is coordinated by at least four oxygen atoms. However, the viewpoint has been debated for decades due to several unexplained bands present in the GeO2 melt Raman spectra. Using in situ Raman spectroscopy and density functional theory (DFT) computation, we have found a [GeOØ2]n (Ø = bridging oxygen) chain structure in a GeO2 melt.

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Threefold coordinated germanium in a GeO2 melt - Nature Communications

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Threefold coordinated germanium in a GeO2 melt - Nature Communications

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